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At a very low temperature, bromobenzene reacts with potassium amide (KNH 2) dissolved in liquid ammonia to form aniline.
The elimination-addition mechanism for the formation of aniline proceeds via a benzyne intermediate.
Cyclization is the simplest way to introduce a conformational constraint often via connecting two suitable sites (head to tail, backbone to side chain, or side chain to side chain).
Thermal electrocyclic ring closure of trans, trans-2, 4-hexadiene forms a cyclobutene with trans
methyl group.
The branch of psychiatry that deals with the science and practice of maintaining and restoring mental health, and of preventing mental disorder through education, early treatment, and public health measures.
The founder of the mental hygiene movement, Clifford Whittingham Beers, wrote an autobiography in 1908 titled A Mind That Found Itself.
It dealt frankly with his mental health struggles and called for reform in the field of mental health treatment.
System parameters are constant values that define the directories where the Data Integration Service stores cache files, reject files, source files, target files, log files, and temporary files.
As is a member of group V and has 5 electrons in its outermost shell.
When Si is doped with group V elements such as As then, Si forms four bonds with As and one extra electron is left free for conduction.
Since the conduction is due to the presence of free electrons, therefore, it is known as n-type semiconductor.
When oil and water are mixed powerfully, they form either oil-in-water (o/w) or water-in-oil (w/o) emulsions.
In o/w emulsions, oil is dispersed in a continuous water phase.
The principal emulsifying agent for o/w emulsion is lampblack or soot.
Other emulsifying agents are the heavy metal salts of the fatty acids, long-chain alcohols, etc.
Measurement of osmotic pressure method is preferred for the determination of molar masses of macromolecules such as proteins and polymers.
This is due to the following two reasons.
The values given by the other colligative properties (elevation in the boiling point, the depression in the freezing point and relative lowering of vapour pressure) are so low that they cannot be measured accurately.
Measurement of osmotic pressure is carried out at room temperature which does not require heating. Heating may change the nature of the polymer.
The primary structure of a protein refers to the linear sequence of amino acids in the polypeptide chain.
The primary structure is held together by covalent bonds such as peptide bonds, which are made during the process of protein biosynthesis or translation.
The primary structure of proteins tells us about the sequence of amino acids in which they are linked.
Collision theory states that when suitable particles of the reactant hit each other with correct orientation, only a certain amount of collisions result in a perceptible or notable change; these successful changes are called successful collisions.
The aspect of successful collision is
Steric requirement
Encounter rate
Minimum energy requirement
Aromatic diazonium ions acts as electrophiles in coupling reactions with activated aromatics such as anilines or phenols.
The substitution normally occurs at the para position, except when this position is already occupied, in which case ortho position is favoured.
The pH of solution is quite important; it must be mildly acidic or neutral, since no reaction takes place if the pH is too low.
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